%0 Journal Article
%T Thermodynamic and Polarization Parameters of Dibenzo-18- crown- 6 in Mixed Methanol Water Solvents
%J American Journal of Polymer Science
%@ 2163-1352
%D 2012
%I 
%R 10.5923/j.ajps.20120203.03
%X The different thermodynamic parameters for the solvation (Free energies, enthalpies, and entropies) ( ¦¤Gs, ¦¤Hs &T¦¤Ss) for dibenzo¨C18¨Ccrown¨C6 in mixed methanol¨Cwater solvents were calculated form the experimental solubility data at different temperatures. From the experimental refractive indices and densities for the saturated solutions, the total polarization (Pt), polarizability (¦Á), induced dipole moment (¦Ì) and the contribution of the electronic permittivity (¦Å¡Þ) were evaluated. The solvation behavior of the crown ether used in these media was discussed in view of the estimated refraction and polarization parameters.Since dibenzo 18-crown-6 has a wide applications in analytical, industrial and biological ones, then the aim of this study is to explain its solvation behaviours in methanol.
%K Crown Ether
%K Solvation
%K Thermodynamic Parameters
%K Polarization
%K Mixed Methanol Water Solvents
%U http://article.sapub.org/10.5923.j.ajps.20120203.03.html