%0 Journal Article %T Crystal structure determination of nanolaminated Ti5Al2C3 by combined techniques of XRPD, TEM and ab initio calculations %A Hui Zhang %A Xiaohui Wang %A Yonghui Ma %A Luchao Sun %A Liya Zheng %A Yanchun Zhou %J Journal of Advanced Ceramics %@ 2227-8508 %D 2012 %I %R 10.1007/s40145-012-0034-9 %X Crystal structure of Ti5Al2C3 was determined by means of X-ray powder diffraction (XRPD), transmission electron microscopy (TEM) and ab initio calculations. In contrast to the already known P63/mmc space group that the MAX phases crystallize, it was demonstrated that the $R\bar 3m$ space group could better satisfy the experimental data. The lattice parameters are a = 0.305 64 nm, c = 4.818 46 nm in a hexagonal unit cell. %K Ti5Al2C3 %K crystal structure %K layered carbides %K transmission electron microscopy (TEM) %U http://link.springer.com/article/10.1007/s40145-012-0034-9