%0 Journal Article %T Kinetic study of the reaction of chlorine atoms with 3-methyl-3-buten-1-ol %A Lei Wang %A MaoFa Ge %A WeiGang Wang %J Chinese Science Bulletin %@ 1861-9541 %D 2009 %I %R 10.1007/s11434-009-0439-1 %X The reaction of a typical unsaturated alcohol, 3-methyl-3-buten-1-ol (MBO331), with Cl atoms, was investigated for the first time. The reaction was investigated using discharged flow-tube coupled with electron impact mass spectrometer. The experiments were performed over the temperature range of 248 K-298 K and at pressure of 1 torr in He as the bath gas. The obtained kinetic data were used to derive the Arrhenius expression: k 1 = (3.47 ¡À 1.21) ¡Á 10 11 exp[(599 ¡À 69)/T] cm3 molecule 1 s 1. Finally, atmospheric lifetimes of the MBO331 with respect to OH radicals, NO3 radicals and Cl atoms have been calculated and the atmospheric implications are considered briefly. %K atmosphereic chemistry %K chloride atoms %K unsaturated alcohols %K gas-phase reaction %K kinetics %U http://link.springer.com/article/10.1007/s11434-009-0439-1