%0 Journal Article
%T Kinetic study of the reaction of chlorine atoms with 3-methyl-3-buten-1-ol
%A Lei Wang
%A MaoFa Ge
%A WeiGang Wang
%J Chinese Science Bulletin
%@ 1861-9541
%D 2009
%I 
%R 10.1007/s11434-009-0439-1
%X The reaction of a typical unsaturated alcohol, 3-methyl-3-buten-1-ol (MBO331), with Cl atoms, was investigated for the first time. The reaction was investigated using discharged flow-tube coupled with electron impact mass spectrometer. The experiments were performed over the temperature range of 248 K-298 K and at pressure of 1 torr in He as the bath gas. The obtained kinetic data were used to derive the Arrhenius expression: k 1 = (3.47 ¡À 1.21) ¡Á 10 11 exp[(599 ¡À 69)/T] cm3 molecule 1 s 1. Finally, atmospheric lifetimes of the MBO331 with respect to OH radicals, NO3 radicals and Cl atoms have been calculated and the atmospheric implications are considered briefly.
%K atmosphereic chemistry
%K chloride atoms
%K unsaturated alcohols
%K gas-phase reaction
%K kinetics
%U http://link.springer.com/article/10.1007/s11434-009-0439-1