%0 Journal Article %T Impedance Spectroscopy of Zr Modified Ba5SmZr3V7O30 Ceramic %A B. K. Giri %A B. B. Mohanty %A P. S. Sahoo %A R. N. P. Choudhary %J Open Access Library Journal %V 5 %N 6 %P 1-5 %@ 2333-9721 %D 2018 %I Open Access Library %R 10.4236/oalib.1104639 %X
Ba5SmZr3V7O30 is a new tungsten bronze structured ceramic compound prepared by substituting Zr at Ti site in Ba5GdTi3V7O30 following high-temperature solid-state reaction route. The X-ray diffraction analysis of the compound confirms the formation of single-phase orthorhombic structures at room temperature. Surface morphology of the compound was studied by scanning electron microscopy. Using a Hioki LCR meter, the effects of temperature (32¡æ - 500¡æ) and frequency (102 - 106 Hz) on structural and electrical properties were studied. Detailed analysis of impedance parameters furnishes a better conception of the electrical properties and type of relaxation processes in the material. The plateau region of the Z¡¯~ frequency plot also indicates the presence of relaxation process in the material. The bulk resistance is observed to be decreased with rise in temperature showing a typical negative temperature coefficient of resistance (NTCR) behavior.
%K Ceramics %K Tungsten Bronze Structure %K Solid-State Reaction %K X-Ray Diffraction %U http://www.oalib.com/paper/5293898