%0 Journal Article
%T Synthesis and Structure of Dimeric Copper (I) Complex from Bis[(2,2¡¯)-dimethyl 2,2¡¯-(1,10-phenanthroline-2,9-diyl) bis(methan-1-yl-1-ylidene)-bis(hydrazinecarbo dithioate)]
%A Md. Arifuzzaman
%A Tasneem A. Siddiquee
%A Mohammad R. Karim
%A Aminul H. Mirza
%A Mohamad A. Ali
%J Crystal Structure Theory and Applications
%P 159-166
%@ 2169-2505
%D 2013
%I Scientific Research Publishing
%R 10.4236/csta.2013.24022
%X <p style=\"text-align:justify;\" class=\"MsoNormal\">
	<span lang=\"EN-US\"><span style=\"font-family:Verdana;\">Metal complex, bis[(2,2¡¯)-dimethyl 2,2¡¯-(1,10-phenanthrline-2,9-diyl)bis(methan-1-yl-1-ylidene)-bis(hydrazinecarrbo dithioate)copper(I)], was synthesized from the reaction of Schiff base, (2,2¡¯)-dimethyl 2,2¡¯-(1,10-phenanthroline-2,9-diyl)bis(methan-1-yl-1-ylidene)-bis(hydrazinecarbo dithioate) and CuCl</span><sub><span style=\"font-family:Verdana;\">2</span></sub><span style=\"font-family:Verdana;\"> at reflux condition in methanol. The copper centers of the complex appear to be reduced. This probably was facilitated by </span><i><span style=\"font-family:Verdana;\">in situ</span></i><span style=\"font-family:Verdana;\"> oxidative formation of disulfide bond at the uncomplexed ligand moieties. Single crystal X-ray diffraction analysis reveals the distorted tetrahedral geometry around the copper centers. This compound crystallizes in the triclinic space group, </span><i><span style=\"font-family:Verdana;\">P-</span></i><span style=\"font-family:Verdana;\">1</span><i> </i><span style=\"font-family:Verdana;\">with crystallographic parameters: </span><i><span style=\"font-family:Verdana;\">a</span></i><span style=\"font-family:Verdana;\"> = 10.006(3) <span style=\"line-height:17px;background-color:#ffffff;font-family:Verdana, Helvetica, Arial;white-space:normal;\">?</span>, </span><i><span style=\"font-family:Verdana;\">b</span></i><span style=\"font-family:Verdana;\"> = 13.272(3) <span style=\"line-height:17px;background-color:#ffffff;font-family:Verdana, Helvetica, Arial;white-space:normal;\">?</span>, </span><i><span style=\"font-family:Verdana;\">c</span></i><span style=\"font-family:Verdana;\"> = 22.123(6) <span style=\"line-height:17px;background-color:#ffffff;font-family:Verdana, Helvetica, Arial;white-space:normal;\">?</span>, </span><i><span style=\"font-family:Verdana;\">¦Á </span></i><span style=\"font-family:Verdana;\">= 85.656(6)¡ã</span></span><span lang=\"EN-US\"><span style=\"font-family:Verdana;\">, </span><i><span style=\"font-family:Verdana;\">¦Â</span></i><span style=\"font-family:Verdana;\"> = 81.656(6)¡ã</span></span><span lang=\"EN-US\"><span style=\"font-family:Verdana;\">, </span><i><span style=\"font-family:Verdana;\">¦Ã</span></i><span style=\"font-family:Verdana;\"> = 73.097(5)¡ã</span></span><span lang=\"EN-US\"><span style=\"font-family:Verdana;\">, </span><i><span style=\"font-family:Verdana;\">¦Ì</span></i><span style=\"font-family:Verdana;\"> = 1.223 mm<span style=\"line-height:15px;\"><sup>-1</sup></span></span><span
%K Schiff Base
%K Copper Complex
%K Metal Complex
%K Phenanthroline
%K Hydrazinecarbo Dithioate
%K X-Ray Diffraction
%U http://www.scirp.org/journal/PaperInformation.aspx?PaperID=41111