%0 Journal Article %T Dichloridobis(2-methoxydibenzo[c,e][1,2]oxaphosphorine-κP)platinum(II) trichloromethane solvate %A Tamá %A s Holczbauer %A Gyö %A rgy Keglevich %A Andrea Keré %A nyi %A Má %A tyá %A s Czugler %J Acta Crystallographica Section E %D 2009 %I International Union of Crystallography %R 10.1107/s1600536809006643 %X The title compound, [PtCl2(C13H11O2P)2]¡¤CHCl3, has a rare PtCl2 bridging of two dibenzooxaphosphorine ligands through the metal atom. The PtII ion is in a slightly distorted square-planar environment. The trichloromethane solvent molecule shows rotational disorder (major occupancy is 0.75) and is placed near to the inversion centre at (1/2, 1/2, 0) in channels parallel to the a axis. The solvent molecule is linked to the complex molecule via intermolecular bifurcated C¡ªH...Cl and C¡ªH...O hydrogen bonds. The crystal structure is further stabilized by ¦Ð¨C¦Ð interactions involving the benzene rings, with a centroid¨Ccentroid distance of 3.658 (8) . %U http://scripts.iucr.org/cgi-bin/paper?S1600536809006643