%0 Journal Article
%T Octakis[2,2′,5,5′-tetrathiafulvalenium(0.5+)] bis[hexamolybdate(2−)] acetonitrile solvate
%A Ikram Zebiri
%A Berkahoum Anak
%A Yacine Djebli
%A Sihem Boufas
%J Acta Crystallographica Section E
%D 2009
%I International Union of Crystallography
%R 10.1107/s1600536809031092
%X The asymmetric unit of the title compound, (C6H4S4)8[Mo6O19]2¡¤CH3CN, contains two halves of two centrosymmetric [Mo6O19]2  hexamolybdate anions, which are each built up from six distorted MoO6 octahedra sharing common edges and one common vertex at the central O atom, six tetrathiafulvalene cations (three of which are located on mirror planes) to balance the charge and a half of an acetonitrile solvent molecule, likewise located on a mirror plane. The two central hexamolybdate O atoms occupy special positions 2a and 2d, respectively. The cations and anions are interlinked through C¡ªH...O contacts.
%U http://scripts.iucr.org/cgi-bin/paper?S1600536809031092