%0 Journal Article
%T Bis[aqua(2,3-naphtho-15-crown-5)sodium] tetrakis(thiocyanato-κN)cobaltate(II)
%A Chengjuan Li
%A Da-Cheng Li
%A Da-Qi Wang
%J Acta Crystallographica Section E
%D 2009
%I International Union of Crystallography
%R 10.1107/s1600536809038641
%X The title complex, [Na(C18H22O5)(H2O)]2[Co(NCS)4], consists of two aqua(2,3-naphtho-15-crown-5)sodium complex cations and one [Co(NCS)4]2  complex anion, which has crystallographic overline 1 symmetry. In the anion, the CoII centre is coordinated by the N atoms of four NCS  ligands in a distorted tetrahedral geometry. In the complex cations, the NaI centre is coordinated by five O atoms of the 2,3-naphtho-15-crown-5 ligand and one water O atom. The complex molecules form a two-dimensional network via weak O¡ªH...S interactions between adjacent cations and anions
%U http://scripts.iucr.org/cgi-bin/paper?S1600536809038641