全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

Adsorption of Anionic Dye Using Cationic Surfactant-Modified Kenaf Core Fibers

DOI: 10.4236/oalib.1103747, PP. 1-18

Subject Areas: Chemical Engineering & Technology, Environmental Chemistry

Keywords: Adsorption, Kenaf Core Fiber, Reactive Red Dye, Anionic Dye, Quaternization

Full-Text   Cite this paper   Add to My Lib

Abstract

Kenaf is a widely cultivated crop, particularly in the tropics. Kenaf core fiber (KCF) is a natural cellulose fiber derived from the plant and it is an important raw material for a variety of products. An attempt was made to chemically quaternized KCF (QKCF) as an adsorbent to increase adsorption affinity towards anionic reactive red-RB dye (RR). KCF was quaternized by treating with (3-chloro-2-hydroxypropyl) trimethylammonium chloride under basic condition. The efficiency of QKCF was investigated by adsorption studies for removing anionic RR dye from aqueous solutions. All experiments were conducted at a batch system and influential parameters cover pH, adsorbent dose, initial dye concentration, agitation speed, temperature, and contact time were investigated. Studies showed that removal efficiency of RR dye increases with increasing the adsorbent dose, agitation speed, temperature, and contact time. The equilibrium data were best represented by the Langmuir isotherm model with maximum adsorption capacity of 169.5 mg/g, and the kinetic data were found to follow the pseudo-second-order kinetic model. In general, QKCF could be suggested as an efficient and low-cost adsorbent for removal anionic dyes.

Cite this paper

Idan, I. J. (2017). Adsorption of Anionic Dye Using Cationic Surfactant-Modified Kenaf Core Fibers. Open Access Library Journal, 4, e3747. doi: http://dx.doi.org/10.4236/oalib.1103747.

References

[1]  Shanmugapriya, A. and Somasundaram, S. (2016) Enhancement of Dye Degradation Activity by Microorganisms—A Review. International Journal of Pharma and Bio Sciences, 7, 122-133.
[2]  George, Z.K., Jie, F. and Kostas, A.M. (2013) The Change from Past to Future for Adsorbent Materials in Treatment of Dyeing Wastewaters. Materials, 6, 5131-5158. https://doi.org/10.3390/ma6115131
[3]  Priyanka, V.P., Mehali, J.M. and Sanjay, P. (2015) Treatment of Industrial Wastewater by Nonviable Biomass—A Review. International Journal of Engineering Research and Applications, 5, 18-22.
[4]  Mondal, S. (2008) Methods of Dye Removal from Dye House Effluent—An Overview. Environmental Engineering Science, 25, 383-396. https://doi.org/10.1089/ees.2007.0049
[5]  Rahman, F. (2016) The Treatment of Industrial Effluents for the Discharge of Textile Dyes Using by Techniques and Adsorbents. Journal of Textile Science & Engineering, 6, 242.
[6]  Gupta, V.K., Kumar, R., Nayak, A., Saleh, T.A. and Barakat, M.A. (2013) Adsorptive Removal of Dyes from Aqueous Solution onto Carbon Nanotubes: A Review. Advances in Colloid and Interface Science, 193-194, 24-34. https://doi.org/10.1016/j.cis.2013.03.003
[7]  Adegoke, K.A. and Bello, O.S. (2015) Dye Sequestration Using Agricultural Wastes as Adsorbents. Water Resources and Industry, 12, 8-24. https://doi.org/10.1016/j.wri.2015.09.002
[8]  El Ghali A., Hassen, B.M. and Sadok, R.M. (2015) Surface Functionalization of Cellulose Fibers Extracted from Juncus acutus L Plant: Application for the Adsorption of Anionic Dyes from Wastewaters. Journal of Engineered Fibers and Fabrics, 10, 52-62.
[9]  Makeswari, M., Santhi, T. and Ezhilarasi, M.R. (2016) Adsorption of Methylene Blue Dye by Citric acid Modified Leaves of Ricinus communis from Aqueous Solutions. Journal of Chemical and Pharmaceutical Research, 8, 452-462.
[10]  Wartelle, L.H. and Marshall, W.E. (2006) Quaternized Agricultural By-Products as Anion Exchange Resins. Journal of Environmental Management, 78, 157-162. https://doi.org/10.1016/j.jenvman.2004.12.008
[11]  Irmak, S. and Ozturk, I. (2010) Hydrogen Rich Gas Production by Thermocatalytic Decomposition of Kenaf Biomass. International Journal of Hydrogen Energy, 35, 5312-5317. https://doi.org/10.1016/j.ijhydene.2010.03.081
[12]  Abu Baker, M.A., Ahmasd, S. and Kuntjoro, W. (2010) The Mechanical Properties of Treated and Untreated Kenaf Fibre Reinforced Epoxy Composite. Journal of Biobased Materials and Bioenergy, 4,159-163. https://doi.org/10.1166/jbmb.2010.1080
[13]  Nakagawa, K., Namba, A., Mukai, S.R., Tamon, H., Ariyadejwanich, P. and Tanthapanichakoon, W. (2004) Adsorption of Phenol and Reactive Dye from Aqueous Solution on Activated Carbons Derived from Solid Wastes. Water Research, 38, 1791-1798. https://doi.org/10.1016/j.watres.2004.01.002
[14]  Pavia, D.V., Lampman, G.M., Kriz, G.S. and Vyvyan, J.R. (2009) Introduction to Spectroscopy. 4th Edition, BROOKS COLE Publishing Company, USA.
[15]  Idan, I.J., Jamil, S.N.A., Abdullah, L.C. and Choong, T.S.Y. (2017) Removal of Reactive Anionic Dyes from Binary Solutions by Adsorption onto Quaternized Kenaf Core Fiber. Interna-tional Journal of Chemical Engineering, 2017, Article ID: 9792657. https://doi.org/10.1155/2017/9792657
[16]  Goswami, P., Blackburn, R.S., El-Dessouky, H.M., Taylor, J. and White, P. (2009) Effect of Sodium Hydroxide Pre-Treatment on the Optical and Structural Properties of Lyocell. European Polymer Journal, 45, 455-465. https://doi.org/10.1016/j.eurpolymj.2008.10.030
[17]  Osma, J.F., Saravia, V., Toca-Herrera, J.L. and Couto, S.R. (2007) Sunflower Seed Shells: A Novel and Effective Low-Cost Adsorbent for the Removal of the Diazo Dye Reactive Black 5 from Aqueous Solutions. Journal of Hazardous Materials, 147, 900-905. https://doi.org/10.1016/j.jhazmat.2007.01.112
[18]  Hameed, B.H. and Ahmad, A.A. (2009) Batch Adsorption of Methylene Blue from Aqueous Solution by Garlic Peel, an Agricultural Waste Biomass. Journal of Hazardous Materials, 164, 870-875. https://doi.org/10.1016/j.jhazmat.2008.08.084
[19]  Gulnaz, O., Kaya, A. and Dincer, S. (2006) The Reuse of Dried Activated Sludge for Adsorption of Reactive Dye. Journal of Hazardous Materials, 134, 190-196. https://doi.org/10.1016/j.jhazmat.2005.10.050
[20]  Patil, S., Patil, J., Renukdas, S. and Patel, N. (2015) Mechanism of Adsorption of Ferrous Ions from Waste Water on Natural Adsorbents. World Journal of Pharmacy and Pharmaceutical Sciences, 4, 767-788.
[21]  Qzdemir, Y., Dogan, M. and Alkan, M. (2006) Adsorption of Cationic Dyes from Aqueous Solutions by Sepiolite. Microporous and Mesoporous Materials, 96, 419-427. https://doi.org/10.1016/j.micromeso.2006.07.026
[22]  Mohammad, M., Hossein, J.M. and Ahmadreza, Y. (20014) Removal of Reactive Dyes from Aqueous Solutions by a Non-Conventional and Low Cost Agricultural Waste: Adsorption on Ash of Aloe Vera Plant. Iranian Journal of Health, Safety & Environment, 1, 117-125.
[23]  Demirbas, E. and Nas, M.Z. (2009) Batch Kinetic and Equilibrium Studies of Adsorption of Reactive Blue 21 by Fly Ash and Sepiolite. Desalination, 243, 8-21. https://doi.org/10.1016/j.desal.2008.04.011
[24]  Metcalf & Eddy, Inc. (2003) Wastewater Engineering, Treatment and Reuse. 4th Edition, McGraw-Hill, New York.
[25]  Bansode, R.R. (2002) Treatment of Organic and Inorganic Pollutants in Municipal Wastewater by Agricultural By-Product Based Granular Activated Carbons (GAC). M.Sc. Thesis, Louisiana State University, Baton Rouge.
[26]  Weber, W.J. (1972) Physico-Chemical Processes for Water Quality Control. Wiley International Science, New York.
[27]  Malik, P.K. (2004) Dye Removal from Wastewater Using Activated Carbon Developed from Sawdust: Adsorption Equilibrium and Kinetics. Journal of Hazardous Materials, 113, 81-88. https://doi.org/10.1016/j.jhazmat.2004.05.022
[28]  Hameed, B.H., Chin, L.H. and Rengaraj, S. (2008) Adsorption of 4-Chlorophenol onto Activated Carbon Prepared from Rattan Sawdust. Desalination, 225, 185-198. https://doi.org/10.1016/j.desal.2007.04.095
[29]  Azizian, S. (2004) Kinetic Models of Sorption: A Theoretical Analysis. Journal of Colloid and Interface Science, 276, 47-52. https://doi.org/10.1016/j.jcis.2004.03.048
[30]  Obaid, M.K., Abdullah, L.C. and Idan, I.J. (2016) Removal of Reactive Orange 16 Dye from Aqueous Solution by Using Modified Kenaf Core Fiber. Journal of Chemistry, 2016, Article ID: 4262578. https://doi.org/10.1155/2016/4262578
[31]  Piccin, J.S., Gomes, C.S., Feris, L.A. and Gutterres, M. (2012) Kinetics and Isotherms of Leather Dye Adsorption by Tannery Solid Waste. Chemical Engineering Journal, 183, 30-38. https://doi.org/10.1016/j.cej.2011.12.013

Full-Text


comments powered by Disqus

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133

WeChat 1538708413