Adsorption kinetics and mechanism of Cypermethrin (CY) and Dichlorovos (DI)
on activated carbons of oil bean seed shell (OBSS), unripe plantain peel (UPP)
and castor bean seed shell (CBSS) systems have been studied. The equilibrium
adsorption isotherms were modelled by Freunlich, Langmuir and Langmuir-Freunlich
(LF) models. Adsorption isotherms of various systems were best described by Langmuir-Freunlich
(LF). Mixed 1,2 order equation (MOE), integrated kinetic Langmuir (IKL), pseudo
second order equation (PSOE), fractal-like mixed 1,2 order equation (F-MOE), and
Boyd and Webbers models were compared and adopted in the analysis of the kinetic
data. The models represented different uptake reduction rate of CY and DI by
various adsorption systems. F-MOE, IKL and MOE models were in agreement with
CY/OBSS, CY/UPP and CY/CBSS system data respectively, hence the conforming models,
whereas IKL, MOE and PSOE were the conforming models for DI/OBSS, DI/UPP and
DI/CBSS adsorption data systems, respectively. The two diffusion models (Boyd
and Webbers) applied confirmed film diffusion pattern as prevailing
transportation pathway for CY and DI onto the adsorbents.
Cite this paper
Uzoije, A. P. , Kamalu, C. O. and Basil, U. (2015). Adsorption Kinetics and Mechanisms of Cypermethrin and Dichlorovos on Heterogeneous Activated Carbon Porous Media. Open Access Library Journal, 2, e1988. doi: http://dx.doi.org/10.4236/oalib.1101988.
Kouras, A.,
Zouboulis, A.,
Samara, C. and Kouimtzis, T. (1998) Removal of Pesticides from Aqueous Solutions by Combined
Physicochemical Processes—The Behaviour of Lindane. Environmental Pollution, 103, 193-202. http://dx.doi.org/10.1016/S0269-7491(98)00124-9
Derylo-Marczewska, A., Blachnio, M., Marczewski, A.W., Swiatkowski, A. and Tarasiuk, B. (2010) Adsorption of Selected Herbicides from Aqueous
Solutions on Activated Carbon. Journal
of Thermal Analysis and Calorimetry, 101, 785-794. http://dx.doi.org/10.1007/s10973-010-0840-7
Balsamo, M., Di
Natale, F.,
Erto, A.,
Lancia, A.,
Montagnaro, F. and Santoro, L. (2011) Cadmium Adsorption by Coal Combustion
Ashes-Based Sorbents Relationship between Sorbent Properties and
Adsorption Capacity. Journal of Hazardous
Materials, 187, 371-378. http://dx.doi.org/10.1016/j.jhazmat.2011.01.029
Farah, J.Y. and El-Gendy, N.Sh. (2013) Performance, Kinetics and Equilibrium in Biosorption
of Anionic Dye Acid Red 14 by the Waste Biomass of Saccharomyces cerevisiae as
a Low-Cost Biosorbent. Turkish
Journal of Engineering and Environmental Sciences, 37, 146-161.
Oladoja, N.A., Aboluwoye, C.O. and Oladimeji, Y.B. (2008) Kinetics and Isotherm
Studies on Methylene Blue Adsorption onto Ground Palm Kernel Coat. Turkish
Journal of Engineering and Environmental Sciences, 32, 303-312.
Marczewski, A.W., Derylo-Marczewska, A. and Slota, A. (2013) Adsorption
and Desorption Kinetics of Benzene Derivativeson Mesoporous Carbon. Adsorption, 19, 391-406. http://dx.doi.org/10.1007/s10450-012-9462-7
Belmouden, M., Assabbane, A.
and Ichou, Y.A. (2001) Removal of 2,4-Dichloro Phenoxyacetic Acid from Aqueous
Solution by Adsorption on Activated Carbon. A Kinetic Study. Annales de Chimie Science des Matériaux, 26, 79-85. http://dx.doi.org/10.1016/S0151-9107(01)80048-9
Marczewski, A.W. (2010) Analysis of Kinetic Langmuir Model. Part I: Integrated
Kinetic Langmuir Equation (IKL): A New Complete Analytical Solution of
the Langmuir Rate Equation. Langmuir,
26, 15229-15238. http://dx.doi.org/10.1021/la1010049
Marczewski, A.W. (2010) Analysis of Kinetic Langmuir Model. Part I:
Integrated Kinetic Langmuir Equation (IKL): A New Complete Analytical Solution
of the Langmuir Rate Equation. Langmuir, 26,
15229-15238. http://dx.doi.org/10.1021/la1010049
Liu, Y. and Shen, L. (2008) From Langmuir Kinetics to First- and
Second-Order Rate Equations for Adsorption. Langmuir, 24, 11625-11630. http://dx.doi.org/10.1021/la801839b
Azizian, S. and Bashiri, H. (2008) Adsorption Kinetics at the Solid/Solution
Interface: Statistical Rate Theory at Initial Times of Adsorption and Close to
Equilibrium. Langmuir, 24, 11669-11676. http://dx.doi.org/10.1021/la802288p
Castillejos, E., Rodríguez-Ramos, I., Soria
Sánchez, M., Munoz, V. and Guerrero-Ruiz,
A. (2011) Phenol Adsorption from Water Solutions Over Microporous and
Mesoporous Carbon Surfaces: A Real Time Kinetic Study. Adsorption, 17,
483-488. http://dx.doi.org/10.1007/s10450-010-9303-5
Marczewski, A.W. (2007) Kinetics and
Equilibrium of Adsorption of Organic Solutes on Mesoporous Carbons. Applied Surface Science, 253, 5818-5826. http://dx.doi.org/10.1016/j.apsusc.2006.12.037
Foo, K.Y. and Hameed,
B.H. (2010) Insights into the Modeling of Adsorption Isotherm Systems. Chemical Engineering Journal, 156, 2-10. http://dx.doi.org/10.1016/j.cej.2009.09.013
Khutia, A.,
Rammelberg, H.U.,
Schmidt, T.,
Henninger, S.
and Janiak, C. (2013) Water Sorption Cycle Measurements on Functionalized MIL-101Cr for Heat
Transformation Application. Chemistry of Materials, 25, 790-798. http://dx.doi.org/10.1021/cm304055k
Juang, R.-S., Lin, S.-H. and Wang, T.-Y. (2003) Removal of Metal Ions from Complexes Solutions
in Fixed Bed Using a Strong Acid Ion Exchange Resin. Chemosphere, 53, 1221-1228. http://dx.doi.org/10.1016/S0045-6535(03)00578-2
Aboul-Magd, A.-A.S. and Al-Haddad, O.A. (2012) Kinetics and Mechanism of Ion Exchange
of Fe3 , Cd2 and Na/H on
Lewatite S-100 Cation Exchanger in Aqueous and Aqueous-Detergent Media. Journal of Saudi Chemical Society, 16,
395-404. http://dx.doi.org/10.1016/j.jscs.2011.02.002
Al-Degs, Y.,
Khraisheh, M.A.M., Allen, S.J. and Ahmad, M.N. (2000) Effect of Carbon Surface Chemistry on
the Removal of Reactive Dyes from Textile Effluent. Water Research, 34, 927-935. http://dx.doi.org/10.1016/S0043-1354(99)00200-6
Esalah, O.J., Weber, M.E. and Vera, J.H. (2000) Removal of Pb(II), Cd(II) and Zn(II) from
Aqueous Solutions by Precipitation with Solution Di-(n-octyl) Phosphate. The
Canadian Journal of Chemical Engineering, 78, 948-954. http://dx.doi.org/10.1002/cjce.5450780512
Amara, M. and Kerdjoudj, H. (2003)
Modification of the Cation Exchange Resin Properties by Impregnation in Polyethyleneimine
Solution: Application to the Separation of Metallic Ions. Talanta, 60, 991-1001. http://dx.doi.org/10.1016/S0039-9140(03)00155-3
Balsamo, M.
and Montagnaro, F. (2015)
Fractal-Like Vermeulen Kinetic Equation for the Description of Diffusion- Controlled
Adsorption Dynamics. The
Journal of Physical Chemistry C, 119, 8781-8785. http://dx.doi.org/10.1021/acs.jpcc.5b01783
Chingombe, P.,
Saha, B. and
Wakeman, R.J. (2006)
Effect of Surface Modification of an Engineered Activated Carbon on the Sorption
of 2,4-Dichlorophenoxy Acetic Acid and Benazolin from Water. Journal of Colloid and Interface Science, 297, 434-442. http://dx.doi.org/10.1016/j.jcis.2005.10.054
Choy, K.K.H., Ko, D.C.K., Cheung, C.W.,
Porter, J.F. and McKay, G. (2004) Film and Intraparticle Mass Transfer during the
Adsorption of Metal Ions onto Bone Char. Journal
of Colloid and Interface Science, 271, 284-295. http://dx.doi.org/10.1016/j.jcis.2003.12.015
Aravindhan, R., Rao, J.R. and
Nair, B.U. (2007)
Removal of Basic Yellow Dye from Aqueous Solution by Adsorption on Green Algae Caulerpa
scalpelliformis. Journal of Hazardous
Material, 142, 68-76. http://dx.doi.org/10.1016/j.jhazmat.2006.07.058
McKay, G. (2001) Solution to the Homogeneous Surface Diffusion
Model for Batch Adsorption Systems Using Orthogonal Collocation. Chemical Engineering Journal, 81,
213-221. http://dx.doi.org/10.1016/S1385-8947(00)00191-1
Ho,
Y.S. and McKay, G.
(2000) Correlative Bio-Sorption Equilibria Model for a Binary Batch System. Chemical Engineering Science, 55,
817-825. http://dx.doi.org/10.1016/S0009-2509(99)00372-3
Hameed, B.H., Mahmoud, D.K. and Ahmad, A.L. (2008) Sorption of Basic Dye from Aqueous
Solution by Pomelo (Citrus grandis)
Peel in a Batch System. Colloids and
Surfaces A: Physicochemical and
Engineering Aspects, 316,
78- 84. http://dx.doi.org/10.1016/j.colsurfa.2007.08.033
Haerifar, M. and Azizian, S. (2012)
Fractal-Like Adsorption Kinetics at the Solid/Solution Interface. The Journal of Physical Chemistry C, 116,
13111-13119. http://dx.doi.org/10.1021/jp301261h
Haerifar, M. and Azizian, S. (2014) Fractal-Like Kinetics for Adsorption on Heterogeneous
Solid Surfaces. The Journal of Physical Chemistry C, 118,
1129-1134. http://dx.doi.org/10.1021/jp4110882
Choy, K.K.H., Porter, J.F. and
McKay, G.
(2004) Film-Pore
Diffusion Models—Analytical and Numerical Solution. Chemical Engineering Science, 59, 501-512. http://dx.doi.org/10.1016/j.ces.2003.10.012
Ponnusam, G. and Srikanth, R. (2012) Wavelet Method to
Film-Pore Diffusion Model for Methylene Blue Adsorption onto Plant Leaf
Powders. Journal of Mathematical
Chemistry, 50, 2775-2785. http://dx.doi.org/10.1007/s10910-012-0063-1