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2-({[4-(1,3-Benzothiazol-2-yl)phenyl]amino}methyl)phenol  [cached]
Kim Potgieter,Thomas Gerber,Eric Hosten,Richard Betz
Acta Crystallographica Section E , 2012, DOI: 10.1107/s1600536811051580
Abstract: In the title compound, C20H16N2OS, the aniline substituent essentially coplanar with the benzothiazole moiety (with an r.m.s. deviation of all fitted non-H atoms of 0.0612 ). The phenol group is almost perpendicular to the benzothiazolylaniline group, with an interplanar angle of 88.36 (2)°. In the crystal, molecules aggregate as centrosymmetric dimers by pairs of O—H...N hydrogen bonds. C—H...O contacts and N—H...π(arene) interactions also occur.
2-[(1,3-Benzothiazol-2-yl)iminomethyl]-4-bromophenol
Hai-Peng Diao,Ti-Jian Sun,Wen Liu
Acta Crystallographica Section E , 2011, DOI: 10.1107/s160053681101275x
Abstract: In the title compound, C14H9BrN2OS, the dihedral angle between the benzene rings is 3.1 (3)°. An intramolecular O—H...N(imine) hydrogen bond occurs. The crystal structure is stabilized by weak intermolecular C—H...O interactions.
Bis(μ-2-{[2-(1,3-benzothiazol-2-yl)hydrazinylidene]methyl}-6-methoxyphenolato)bis[dinitratodysprosium(III)] methanol disolvate
Xuebin Xu,Shuai Ding,Si Shen,Jinkui Tang
Acta Crystallographica Section E , 2011, DOI: 10.1107/s1600536811019118
Abstract: In the centrosymmetric dinuclear title compound, [Dy2(C15H12N3O2S)2(NO3)4]·2CH3OH, the two DyIII atoms are coordinated by two deprotonated 2-{[2-(1,3-benzothiazol-2-yl)hydrazinylidene]methyl}-6-methoxyphenol ligands and four nitrate ions, all of which are chelating. The crystal packing is stabilized by intermolecular N—H...O hydrogen bonds and weak O—H...O interactions, forming a two-dimensional network parallel to (010).
cis-Bis[2-(1,3-benzothiazol-2-yl)-1-(4-fluorophenyl)ethenyl](pentane-2,4-dionato-κ2O,O′)iridium(III)  [cached]
Guo-Yong Xiao,Peng Lei,Hai-Jun Chi,Zhi-Zhi Hu
Acta Crystallographica Section E , 2009, DOI: 10.1107/s1600536809010204
Abstract: In the title compound, [Ir(C15H9FNS)2(C5H7O2)], the Ir atom is hexacoordinated by three chelating ligands, with two cyclometalated 2-(1,3-benzothiazol-2-yl)-1-(4-fluorophenyl)ethenyl ligands showing N,C-bidentate coordination and an O,O′-bidenate pentane-2,4-dionate anion, thereby forming a distorted octahedral enviroment.
4-(1,3-Benzothiazol-2-yl)-5-methyl-2-phenyl-1-propynyl-1H-pyrazol-3(2H)-one
Imane Chakib,Abdelfettah Zerzouf,Hafid Zouihri,El Mokhtar Essassi
Acta Crystallographica Section E , 2010, DOI: 10.1107/s1600536810040328
Abstract: The title compound, C20H15N3OS, is a 1H-pyrazol-3(2H)-one having aromatic 4-(1,3-benzothiazol-2-yl) and 2-phenyl substituents. The five-membered ring and the fused-ring system are close to planar, the r.m.s. deviations being 0.025 and 0.005 , respectively. The five-membered ring is aligned at 67.5 (1)° with respect to the phenyl ring and at 4.7 (1)° with respect to the fused-ring system. In the crystal, adjacent molecules are linked through the acetylenic H atom by a C—H...O hydrogen bond into C(8) chains propagating in [010].
1-Allyl-4-(1,3-benzothiazol-2-yl)-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one
Imane Chakib,Abdelfettah Zerzouf,Hafid Zouihri,El Mokhtar Essassi
Acta Crystallographica Section E , 2010, DOI: 10.1107/s1600536810040316
Abstract: The title compound, C20H17N3OS, is a 1H-pyrazol-3(2H)-one having aromatic 4-(1,3-benzothiazol-2-yl)- and 2-phenyl substituents. The five-membered ring and fused ring system are planar, the r.m.s. deviations being 0.021 and 0.005 , respectively. The five-membered ring is aligned at 7.9 (2)° with respect to the fused-ring system. The allyl and phenyl parts of the molecule are both disordered over two positions in a 1:1 ratio. Weak intermolecular C—H...O hydrogen bonding is present in the crystal structure.
2-(1,3-Benzothiazol-2-ylsulfanyl)-1-phenylethanone
Hossein Loghmani-Khouzani,Dariush Hajiheidari,Ward T. Robinson,Noorsaadah Abdul Rahman
Acta Crystallographica Section E , 2009, DOI: 10.1107/s1600536809033121
Abstract: In the molecule of the title compound, C15H11NOS2, the 1,3-benzothiazole ring is oriented at a dihedral angle of 6.61 (6)° with respect to the phenyl ring. In the crystal structure, intermolecular C—H...O interactions link the molecules in a herring-bone arrangement along the b axis and π–π contacts between the thiazole and phenyl rings [centroid–centroid distance = 3.851 (1) ] may further stabilize the structure.
(E)-2-[(3-Fluorophenyl)iminomethyl]-4-(trifluoromethoxy)phenol
Yelda Bingöl Alpaslan,Gökhan Alpaslan,Ayşen Ağar,Şamil Işık
Acta Crystallographica Section E , 2010, DOI: 10.1107/s1600536810002989
Abstract: The title compound, C14H9F4NO2, is a Schiff base which adopts the phenol–imine tautomeric form in the solid state. The H atom is located on the hydroxy O atom rather than on the N atom. This H atom is involved in a strong intramolecular O—H...N hydrogen bond. The molecule is almost planar, the angle between the benzene rings being 2.14 (13)°.
(E)-2-Ethoxy-6-[(4-ethoxyphenyl)iminomethyl]phenol  [cached]
Arzu Özek,Başak Koşar,Çiğdem Albayrak,Orhan Büyükgüngör
Acta Crystallographica Section E , 2010, DOI: 10.1107/s1600536810006434
Abstract: In the asymmetric unit of the title compound, C17H19NO3, there are three independent molecules, which are align nearly parallel to each other and adopt the phenol-imine tautomeric form. In each molecule, an intramolecular O—H...N hydrogen bond results in the formation of an S(6) ring motif. The dihedral angles between the aromatic rings in the three independent molecules are 13.55 (2), 21.24 (2) and 46.26 (1)°. C—H...π interactions are also observed in the crystal structure.
(E)-2-[(4-Chlorophenyl)iminomethyl]-4-(trifluoromethoxy)phenol
Marife Tüfekçi,Yelda Bingöl Alpaslan,Mustafa Macit,Ahmet Erdönmez
Acta Crystallographica Section E , 2009, DOI: 10.1107/s1600536809040690
Abstract: The title compound, C14H9ClF3NO2, crystallizes in a phenol–imine tautomeric form, with a strong intramolecular O—H...N hydrogen bond. The dihedral angle between the two benzene rings is 47.62 (9)°. In the crystal, molecules are linked into chains along the c axis by C—H...O hydrogen bonds, and weak C—H...π interactions involving both benzene rings are also observed.
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