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Methyl 3-(4-methylbenzylidene)carbazate
Yu-Feng Li,Fu-Gong Zhang,Fang-Fang Jian
Acta Crystallographica Section E , 2010, DOI: 10.1107/s160053681001799x
Abstract: The title compound, C10H12N2O2, was prepared by the reaction of methyl carbazate and 4-methylbenzaldehyde. The dihedral angle between the benzene ring and the carbazate fragment is 20.86 (10)°. In the crystal structure, molecules are linked by intermolecular N—H...O hydrogen bonds.
Jian-Gang Wang,Fang-Fang Jian,Yu-Feng Ding
Acta Crystallographica Section E , 2008, DOI: 10.1107/s1600536808025105
Abstract: The title compound, C9H10N4O2S, was prepared by the reaction of 1-(4-nitrophenyl)ethanone and thiosemicarbazide in ethanol at 367 K. There are weak intermolecular N—H...S and N—H...O hydrogen-bonding interactions in the crystal structure involving the amine and nitrile groups, respectively, as donors.
3-({4-[(2-Methylbenzylidene)amino]-5-sulfanylidene-1H-1,2,4-triazol-3-yl}methyl)-1,3-benzoxazol-2(3H)-one  [cached]
Abdullah Ayd?n,Nuray Hekimo?lu,Mehmet Akkurt,Tijen ?nkol
Acta Crystallographica Section E , 2013, DOI: 10.1107/s1600536812051458
Abstract: In the title compound, C18H15N5O2S, a weak intramolecular C—H...S hydrogen bond results in a small dihedral angle of 3.71 (9)° between the methylphenyl and triazole rings, which, in turn, form dihedral angles of 80.09 (8) and 77.32 (8)°, respectively, with the benzoxazolone mean plane. In the crystal, N—H...O hydrogen bonds link molecules into chains along [001], and weak C—H...N hydrogen bonds and π–π interactions between the five- and six-membered rings [centroid–centroid distances = 3.5074 (11) and 3.616 (1) ] consolidate the crystal packing.
Muhammad Shafiq,William T. A. Harrison,Islam Ullah Khan,Ejaz
Acta Crystallographica Section E , 2012, DOI: 10.1107/s1600536812039529
Abstract: In the title compound, C17H17N3O2S, the dihedral angle between the aromatic rings is 6.3 (5)° and the C=N—N=C group is statistically planar [torsion angle = 179.8 (8)°]. The conformation of the thiazine ring is an envelope, with the S atom displaced by 0.823 (9) from the mean plane of the other five atoms (r.m.s. deviation = 0.012 ). In the crystal, C—H...O interactions link the molecules into C(5) chains propagating along [101]. The chains are consolidated by weak aromatic π–π stacking between the benzene and toluene rings [centroid-to-centroid separation = 3.826 (5) and interplanar angle = 6.3 (4)°].
(E)-1-[4-(Dimethylamino)benzylidene]thiosemicarbazide  [cached]
Yuying Sun,Shizhou Fu,Junhong Zhang,Xiao Wang
Acta Crystallographica Section E , 2009, DOI: 10.1107/s1600536808043778
Abstract: In the title molecule, C10H14N4S, the thiorea plane and benzene ring form a dihedral angle of 16.0 (3) . In the crystal structure, intermolecular N—H...S hydrogen bonds link the molecules into ribbons extended in the [100] direction; these incorporate inversion dimers.
4-Methyl-1-(3-pyridylmethylidene)thiosemicarbazide  [cached]
Rongchun Li
Acta Crystallographica Section E , 2010, DOI: 10.1107/s1600536810048853
Abstract: All the non-H atoms of the title compound, C8H10N4S, lie on a crystallographic mirror plane and an intramolecular N—H...N hydrogen bond helps to stabilize the molecular conformation. In the crystal, molecules are linked through intermolecular N—H...N hydrogen bonds, forming zigzag C(7) chains along the a axis.
Jian-Chao Wu,Su-Xia Gao,Wen-Kui Dong,Jun-Feng Tong
Acta Crystallographica Section E , 2009, DOI: 10.1107/s1600536809042147
Abstract: The title bisoxime compound, C19H22N2O2, synthesized by the reaction of 4-methyl-2-hydroxybenzaldehyde with 1,3-bis(aminooxy)propane in ethanol, adopts a V-shaped conformation. The dihedral angle between the rings is 84.59 (3)°. The molecule is disposed about a crystallographic twofold rotation axis, with one C atom lying on the axis. In the crystal, molecules are packed by C—H...π(Ph) interactions, forming chains.
Hana Bashir Shawish,M. Jamil Maah,Seik Weng Ng
Acta Crystallographica Section E , 2010, DOI: 10.1107/s1600536810015850
Abstract: In the title molecule, C8H9N3O3S, the thiosemicarbazide =N—NH—C(=S)—NH— fragment is twist a different degree of twist in the three independent molecules [dihedral angles = 7.6 (1), 11.6 (1) and 20.7 (1)°]. Intramolecular O—H...N and O—H...O hydrogen bonds occur. In the crystal, the hydroxy and amino groups are hydrogen-bond donors and the O—H...O, O—H...S and N—H...O hydrogen bonds generate a layer motif.
A Novel Hydrazinecarbothioamide as a Potential Corrosion Inhibitor for Mild Steel in HCl  [PDF]
Ahmed A. Al-Amiery,Abdul Amir H. Kadhum,Abu Bakar Mohamad,Sutiana Junaedi
Materials , 2013, DOI: 10.3390/ma6041420
Abstract: 2-(1-methyl-4-((E)-(2-methylbenzylidene)amino)-2-phenyl-1H-pyrazol-3(2H)-ylidene)-hydrazineecarbothioamide (HCB) was synthesized as a corrosion inhibitor from the reaction of 4-aminoantipyrine, thiosemicarbazide and 2-methylbenzaldehyde. The corrosion inhibitory effects of HCB on mild steel in 1.0 M HCl were investigated using potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS). The results showed that HCB inhibited mild steel corrosion in acidic solution and inhibition efficiency increased with an increase in the concentration of the inhibitor. The inhibition efficiency was up to 96.5% at 5.0 mM. Changes in the impedance parameters suggested that HCB adsorbed on the surface of mild steel, leading to the formation of a protective film. The novel corrosion inhibitor synthesized in the present study was characterized using Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR) spectral data.
An NMR Study on 1-(4-Nitro-phenylaminoacetyl)-4-phenylacetyl Thiosemicarbazide

LI Ying-jun,SUN Ya-zhen,XU Yong-ting,WEN Li-ping,ZHANG Zhi-guang,HOU Ni-bo,SUN Xiao-xiao,

波谱学杂志 , 2006,
Abstract: Having the potential of being used as a plant-growth regulator,1-(4-nitro-phenylaminoacetyl)-4-phenylacetyl thiosemicarbazide was synthesized.Its()~1H and()~(13)C NMR chemical shifts were assigned by 2D NMR techniques.
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