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4-Fluoro-2-[(3-methylphenyl)iminomethyl]phenol  [cached]
Alice Brink,Hendrik G. Visser,Andreas Roodt
Acta Crystallographica Section E , 2012, DOI: 10.1107/s1600536812010513
Abstract: The title compound, C14H12FNO, crystallizes as the trans phenol–imine tautomer. The two benzene rings are essentially coplanar, being inclined to one another by 9.28 (7)°. This is at least in part due to the intramolecular O—H...N hydrogen bond between the hydroxy O atom and the imine N atom. The crystal structure is stabilized by an array of weak C—H...O and C—H...F interactions, which link the molecules into a stable three-dimensional network.
Bis{(E)-2-methoxy-6-[(4-methylphenyl)iminomethyl]phenolato}zinc(II)
Hui-Duo Xian,Jian-Feng Liu,Hua-Qiong Li,Guo-Liang Zhao
Acta Crystallographica Section E , 2008, DOI: 10.1107/s1600536808033102
Abstract: The title compound, [Zn(C15H14NO2)2], contains a four-coordinate Zn atom located on a twofold rotation axis that exhibits a distorted tetrahedral geometry by two phenolate O atoms and two azomethine N atoms of the Schiff base 2-methoxy-6-[(4-methylphenyl)iminomethyl]phenolate ligands.
Bis{1-[(4-methylphenyl)iminomethyl]-2-naphtholato-κ2N,O}copper(II)  [cached]
Peihua Zhu,Hongyan Wang,Yan Wang,Yanli Chen
Acta Crystallographica Section E , 2010, DOI: 10.1107/s1600536810030667
Abstract: In the title complex, [Cu(C18H14NO)2], the CuII ion lies on an inversion center and is coordinated in a slightly distorted square-planar environment. The 1-[(4-methylphenyl)iminomethyl]-2-naphtholate ligands are coordinated in a trans arrangement with respect to the N and O atoms.
Bis{1-[(4-methylphenyl)iminomethyl]-2-naphtholato-κ2N,O}nickel(II)  [cached]
Quanbo Wang,Jianzhuang Jiang,Peihua Zhu
Acta Crystallographica Section E , 2011, DOI: 10.1107/s1600536811010087
Abstract: In the title complex, [Ni(C18H14NO)2], the NiII ion lies on an inversion center and is coordinated in a slightly distorted square-planar environment. The 1-[(4-methylphenyl)iminomethyl]-2-naphtholate ligands are coordinated in a trans arrangement with respect to the N and O atoms. In the symmetry-unique ligand, the dihedral angle between the naphthalene ring system and the benzene ring of the methylphenyl group is 49.03 (7)°.
4-{2-Methoxy-6-[(4-methylphenyl)iminomethyl]phenoxy}phthalonitrile
Serap Yazıcı,Abdullah Akkaya,Erbil Ağar,smet Şenel
Acta Crystallographica Section E , 2009, DOI: 10.1107/s1600536809015402
Abstract: In the molecule of the title compound, C23H17N3O2, the methoxyphenyl ring is oriented at dihedral angles of 13.34 (12) and 88.83 (12)° with respect to the methylphenyl and phthalonitrile rings, respectively; the dihedral angle between methylphenyl and phthalonitrile rings is 89.67 (10)°. In the crystal structure, weak intermolecular C—H...N interactions link molecules into chains. A weak C—H...π interaction is also found..
Bis{2,6-bis[(2-hydroxy-5-methylphenyl)iminomethyl]pyridine} monohydrate  [cached]
Muhammet Kose,Vickie McKee
Acta Crystallographica Section E , 2011, DOI: 10.1107/s1600536811045399
Abstract: The title compound, 2C21H19N3O2·H2O, was synthesized by a Schiff base condensation of 2,6-diformylpyridine with 2-amino-4-methylphenol in ethanol. In the crystal, two molecules of 2,6-bis[(2-hydroxy-5-methylphenyl)iminomethyl]pyridine dimerize via hydrogen bonding to a water molecule, which lies on a twofold axis. There are also intramolecular phenol–imine hydrogen bonds. The dimers are further linked via π–π (phenyl–pyridine) [centroid–centroid distance = 3.707 (2) ] and π–π edge-to-edge [3.392 (2) ] interactions. The dihedral angles between the central ring and the two pendant rings are 11.46 (8) and 2.06 (8)° while the pendant rings make a dihedral angle of 10.14 (8)°.
Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ2O,O′}tris(thiocyanato-κN)cerium(III)  [cached]
Jian-Feng Liu,Hui-Duo Xian,Guo-Liang Zhao
Acta Crystallographica Section E , 2009, DOI: 10.1107/s1600536809016808
Abstract: The asymmetric unit of the title compound, [Ce(NCS)3(C15H15NO2)3], contains three Schiff base 2-methoxy-6-[(4-methylphenyl)iminomethyl]phenol (HL) ligands and three independent thiocyanate ions that coordinate the cerium ion via their N atoms. The protonated imine N atoms are involved in an intramolecular hydrogen bond with the respective phenoxide group. The Ce(III) ion exhibits a coordination number of nine.
Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ2O,O′}tris(thiocyanato-κN)praseodymium(III) monohydrate
Jian-Feng Liu,Jia-Lu Liu,Guo-Liang Zhao
Acta Crystallographica Section E , 2009, DOI: 10.1107/s1600536809038823
Abstract: The asymmetric unit of title compound, [Pr(NCS)3(C15H15NO2)3]·H2O, consists of three Schiff base 2-methoxy-6-[(4-methylphenyl)iminomethyl]phenol (HL) ligands, three independent thiocyanate anions and an uncoordinated water molecule. The PrIII ion is nine-coordinated. The thiocyanate anions coordinate to the PrIII ion via the N atoms and the three HL ligands chelate the PrIII ion via the phenoxy and methoxy O atoms. The protonated imine N atoms are involved in intramolecular hydrogen bonds with the phenolate groups.
4-[(E)-(4-Methylphenyl)iminomethyl]phenol  [cached]
L. Jothi,G. Vasuki,R. Ramesh Babu,K. Ramamurthi
Acta Crystallographica Section E , 2012, DOI: 10.1107/s1600536812007635
Abstract: In the title compound, C14H13NO, the two rings show significant deviation from coplanarity, with a dihedral angle between the two planes of 49.40 (5)°. The hydroxy group is involved in an intermolecular O—H...N hydrogen bond, forming an extended one-dimensional zigzag chain along (001).
2-[4-(Morpholin-4-ylmethyl)phenyl]benzonitrile  [cached]
Gangadhar Y. Meti,R. R Kamble,A. J. Ravi,H. K. Arunkashi
Acta Crystallographica Section E , 2013, DOI: 10.1107/s1600536812050957
Abstract: In the title compound, C18H18N2O, the morpholine ring adopts a chair conformation with the exocyclic N—C bond in an equatorial orientation. The dihedral angles between the central benzene ring and the morpholine ring (all atoms) and the cyanobenzene ring are 87.87 (7) and 52.54 (7)°, respectively. No significant intermolecular interactions are observed in the crystal structure.
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