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Three New -CF3, -CN Containing π -Conjugated Heteroaromatic Compounds: Synthesis, Crystal Structure and Photoelectronic Properties

DOI: 10.4236/csta.2018.73003, PP. 33-45

Keywords: Organic Semiconducting Material, Knoevenagel Condensation, X-Ray Analysis, π-Conjugated Materials

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Abstract:

Three new π-conjugated hetero aromatic materials consisting of pyridine 3a, furan 3b, and thiophene 3c have been synthesized by Knoevenagel condensation reaction. These molecules have been characterized by 1H NMR, EI-MS and single crystal X-ray diffraction analysis. Molecule 3a crystallized under monoclinic system with space group C2/c, molecule 3b crystallized under triclinic system with space group P-1 and the molecule 3c crystalized under triclinic system with space group P-1. The optoelectronic properties of these compounds have been studied.Molecules 3a, 3b and 3c showed strong absorption maxima wavelengths at 300, 419 and 418 nm, respectively. The molar extinction coefficients (ε) of the compounds 3a, 3b

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