围绕色谱、毛细管电泳与光谱、质谱的联用技术及其应用，综述了铅形态分析的研究进展，展望了铅形态分析的发展前景。 A review on research progress of speciation analysis of lead was presented, with emphasis on the applications of chromatography and capillary electrophoresis hyphenated with spectrometry and mass spectrometry. The prospect of lead speciation analysis was also discussed.
Beceiro-González, E., Guimaraes, A. and Alpendurada, M.F. (2009) Optimisation of a headspace-solid-phase micro- extraction method for simultaneous determination of organometallic compounds of mercury, lead and tin in water by gas chromatography-tandem mass spectrometry. Journal of Chromatography A, 1216, 5563-5569.
Pe？alver, R., Campillo, N. and Hernández-Córdoba, M. (2011) Comparison of two derivatization reagents for the simultaneous determination of organolead and organomanganese compounds using solid-phase microextraction followed by gas chromatography with atomic emission detection. Talanta, 87, 268-275.
Baena, J.R., Gallego, M. and Valcárcel, M. (2001) Comparison of three coupled gas chromatographic detectors (MS, MIP-AES, ICP-TOFMS) for organolead speciation analysis. Analytical Chemistry, 73, 3927-3934.
Leal-Granadillo, I.A., Alonso, J.I.G. and Sanz-Medel, A. (2000) Determination of the speciation of organolead compounds in airborne particulate matter by gas chromatography-inductively coupled plasma spectrometry. Analytica Chimica Acta, 423, 21-29.
Salih, B. (2000) Speciation of inorganic and organolead compounds by gas chromatography-atomic absorption spectrometry and the determination of lead species after pre-concentration onto di-phenylthiocarbazone-anchored polymeric microbeads. Spectrochimica Acta Part B, 55, 1117-1127.
Campillo, N., Cacho, J.I., Marín, J., Vi？as, P. and Hernández-Córdoba, M. (2014) Utrasound-assisted emulsification microextraction of organolead and organomanganese compounds from seawater and their determination by GC-MS. Microchimica Acta, 181, 97-104.
Parkinson, D.R., Bruheim, I., Christ, I. and Pawliszyn, J. (2004) Full automation of derivatiza-tion—Solid-phase microextraction-gas chromatography-mass spectrometry with a dual-arm system for the determination of organometallic compounds in aqueous samples. Journal of Chromatography A, 1025, 77-84.
Pons, B., Carrera, A. and Nerín, C. (1998) Speciation of ionic alkyllead compounds in human urine by gas chromatography-mass spectrometry after butylation through a Grignard reaction. Journal of Chromatography B: Biomedical Sci- ences and Applications, 716, 139-145.
Heisterkamp, M. and Adams, F.C. (2001) Gas chromatography-inductively coupled plasma—Time-of-flight mass spectrometry for the speciation analysis of organolead compounds in environmental water samples. Fresenius’ Journal of Analytical Chemistry, 370, 597-605.
Centineo, G., González, E.B. and Sanz-Medel, A. (2004) Multielemental speciation analysis of organometallic compounds of mercury, lead and tin in natural water samples by headspace-solid phase microextraction followed by gas chromatography-mass spectrometry. Journal of Chromatography A, 1034, 191-197.
Zú？iga, M.C., Jover, E., Arancibia, V. and Bayona, J.M. (2009) Development of a methodology for the simultaneous determination of inorganic and organolead compounds using supercritical fluid extraction followed by gas chromatography-mass spectrometry and its application to environmental matrices. Talanta, 80, 504-510.
Jitaru, P., Infante, H.G. and Adams, F.C. (2004) Simultaneous multi-elemental speciation analysis of organometallic compounds by solid-phase microextraction and multicapillary gas chromatography hyphenated to inductively coupled plasma-time of flight-mass spectrometry. Journal of Analytical Atomic Spectrometry, 19, 867-875.
Ebdon, L., Hill, S.J. and Rivas, C. (1998) Lead speciation in rainwater by isotope dilution-high performance liquid chromatography-inductively coupled plasma-mass spectrometry. Spectrochimica Acta Part B: Atomic Spectroscopy, 53, 289-297.
Mester, Z., Lord, H. and Pawliszyn, J. (2000) Speciation of trimethyllead and triethyllead by in-tube solid phase microextraction high-performance liquid chromatography electrospray ionization mass spectrometry. Journal of Analytical Atomic Spectrometry, 15, 595-600.
Chang, L.F., Jiang, S.J. and Sahayam, A.C. (2007) Speciation analysis of mercury and lead in fish samples using liquid chromatography-inductively coupled plasma mass spectrometry. Journal of Chromatography A, 1176, 143-148.
Shum, S.C.K., Pang, H. and Houk, R.S. (1992) Speciation of mercury and lead compounds by microbore column liquid chromatography-inductively coupled plasma mass spectrometry with direct injection nebulization. Analytical Chemistry, 64, 2444-2450.
AL-Rashdan, A., Vela, N.P. and Caruso, J.A. (1992) Lead speciation by gradient high-performance liquid chromatography with inductively coupled plasma mass spectrometric detection. Journal of Analytical Atomic Spectrometry, 7, 551-555.
Brown, A.A., Ebdon, L. and Hill, S.J. (1994) Development of a coupled liquid chromatography-isotope dilution inductively coupled plasma mass spectrometry method for lead speciation. Analytica Chimica Acta, 286, 391-399.
Liu, W. and Lee, H.K. (1998) Use of triethylenetetraminehexaacetic acid combined with field-amplified sample injection in speciation analysis by capillary electrophoresis. Analytical Chemistry, 70, 2666-2675.
Chen, Z., Owens, G., Kim, K.R. and Naidu, R. (2007) Confirmation of lead aminocarboxylic complex formation using electrospray ionization mass spectrometry and speciation by anion-exchange chromatography coupled with ICP-MS. Analytica Chimica Acta, 599, 163-169.
Chen, W.H., Lin, S.Y. and Liu, C.Y. (2000) Capillary electrochromatographic separation of metal ion species with on- line detection by inductively coupled plasma mass spectrometry. Analytica Chimica Acta, 410, 25-35.