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Crystallization and Characterization of a New Fluorescent Molecule Based on Schiff Base

DOI: 10.4236/jcpt.2013.31004, PP. 28-30

Keywords: Slow Evaporation, X-Ray Diffraction, Schiff Base, Fluorescence Quenching, Cu2+

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Abstract:


In this analysis, the single crystal of schiff base has been synthesized and the purity of material has been increased by repeated recrystallization process. Single crystal was grown by adopting the method growing in a slow evaporation solution using ethanol as solvent at room temperature. A new fluorescent molecule based on Schiff base has been synthesised and its binding properties investigated by fluorescence spectroscopy to show that it can selectively bind Cu2+ with fluorescence quenching.


References

[1]  S. Yamada, “Advancement in Stereochemical Aspects of Schiff Base Metal Complexes,” Coordination Chemistry Reviews, Vol. 190-192, 1999, pp. 537-555. doi:10.1016/S0010-8545(99)00099-5
[2]  S. Koizumi, M. Nihei, M. Nakano and H. Oshio, “Antiferromagnetic FeIII6 Ring and Single-Molecule Magnet MnII3MnIII4 Wheel,” Inorganic Chemistry, Vol. 44, No. 5, 2005, pp. 1208-1210. doi:10.1021/ic0484203
[3]  V. T. Dao, C. Gaspard, M. Mayer, G. H. Werner, S. N. Nguyen and R. J. Michelot, “Synthesis and Cytotoxicity of Gossypol Related Compounds,” European Journal of Medicinal Chemistry, Vol. 35, No. 9, 2000, pp. 805-813. doi:10.1016/S0223-5234(00)00165-3
[4]  D. Sriram, P. Yogeeswari, N. S. Myneedu and V. Saraswat, “Abacavir Prodrugs: Microwave-Assisted Synthesis and Their Evaluation of Anti-HIV Activities,” Bioorganic & Medicinal Chemistry Letters, Vol. 16, No. 8, 2006, pp. 2127-2129. doi:10.1016/j.bmcl.2006.01.050
[5]  A. Soliman and W. Linert, “Structural Features of ONSDonor Salicylidene Schiff Base Complexes,” Monatsheftefur Chemie Chemical Monthly, Vol. 138, No. 3, 2007, pp. 175-189.
[6]  A. Giuseppe, C. Annalinda, L. Elisa and S. Domenico, “Synthesis, Characterization of a Novel Calixarene Having Dipyridyl Pendants and Study of Its Complexes with Cu2+ and Co2+,” Tetrahedron Letters, Vol. 44, No. 29, 2003, pp. 5415-5418. doi:10.1016/S0040-4039(03)01319-4
[7]  Z. Dehua, “Synthesis and Binding Properties of a New Fluorescent Molecular Clip Based on 2-Ethyl Cyanoacrylate,” Journal of Chemical Research, Vol. 34, 2010, pp. 635-636.
[8]  E. E. Naser, G. T. Siang, S. Y. Chin and A. Rohana, “6,6’-Di-tert-butyl-2,2’-[1,2-phenylenebis(nitrilomethylidyne)]diphenol,” Acta Crystallographica, Vol. E65, 2009, pp. o3142-o3143.

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