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环境科学学报 2011
Heterogeneous reaction of NO2 on the surface of kaolinite particles
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Abstract:
The studies of heterogeneous reactions on kaolinite,typically a 1:1 layered aluminosilicate,are necessary to understanding heterogeneous reactions on clay minerals.Using diffuse reflectance infrared Fourier transform spectroscopy(DRIFTS),we investigated the heterogeneous reaction of NO2 on the surface of kaolinite particles.It is found that NO 3-and NO 2-were generated on the surface via the disproportionate reaction.Relative humidity played an important role in the heterogeneous reaction of NO2 and kaolini...